No. You should drop off your packed and labeled bike at a UPS Store®. See also “How do I ship to or from a UPS Store®?”
If you instead drop off your shipments at other locations such as a UPS Access Point®, various Retail Chains, Authorized Shipping Outlets (ASO) or UPS Authorized Service Providers, and it is accepted, it will still travel through the UPS carrier system; however, you may not be able to get a receipt, and these locations may not have a daily pickup, so your shipment may take longer to deliver.